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SJAB1958 Guest
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Posted: Fri Jun 01, 2007 10:58 am Post subject: Catalysts Query |
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What is the simplest organic molecule that can catalyse a reaction
from which the same molecule emerges as one of the products? |
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Stephan Bird Guest
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Posted: Fri Jun 01, 2007 7:11 pm Post subject: Re: Catalysts Query |
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On Thu, 31 May 2007 22:58:12 -0700, in
1180677492.424172.144130@k79g2000hse.googlegroups.com SJAB1958
<balfres@hotmail.com> wrote:
| Quote: |
What is the simplest organic molecule that can catalyse a reaction
from which the same molecule emerges as one of the products?
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You might want to look into Soai autocatalysis, e.g
<http://dx.doi.org/10.1038/378767a0>
Stephan
--
Stephan Bird MChem(Hons) AMRSC
Currently in Caernarfon, Wales |
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SJAB1958 Guest
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Posted: Fri Jun 01, 2007 8:11 pm Post subject: Re: Catalysts Query |
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On 1 Jun, 15:11, Stephan Bird <stephan.j.b...@mad.scientist.comREMOVE>
wrote:
Thanks for the link, pity I cannot access the remainder of the
article, still it is a pointer in the right direction. |
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Ron Jones Guest
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Posted: Fri Jun 01, 2007 11:35 pm Post subject: Re: Catalysts Query |
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SJAB1958 wrote:
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What is the simplest organic molecule that can catalyse a reaction
from which the same molecule emerges as one of the products?
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aryl bromide + CuCN to aryl cyanide + CuBr
- usual cat is pyridine, dmf, etc., but the product often works better.
--
Ron Jones
Process Safety & Development Specialist
Don't repeat history, unreported chemical lab/plant near misses at
http://www.crhf.org.uk
Only two things are certain: The universe and human stupidity; and I'm not
certain about the universe. ~ Albert Einstein |
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