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Catalysts Query

 
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SJAB1958
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PostPosted: Fri Jun 01, 2007 10:58 am    Post subject: Catalysts Query Reply with quote

What is the simplest organic molecule that can catalyse a reaction
from which the same molecule emerges as one of the products?
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Stephan Bird
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PostPosted: Fri Jun 01, 2007 7:11 pm    Post subject: Re: Catalysts Query Reply with quote

On Thu, 31 May 2007 22:58:12 -0700, in
1180677492.424172.144130@k79g2000hse.googlegroups.com SJAB1958
<balfres@hotmail.com> wrote:

Quote:
What is the simplest organic molecule that can catalyse a reaction
from which the same molecule emerges as one of the products?

You might want to look into Soai autocatalysis, e.g
<http://dx.doi.org/10.1038/378767a0>

Stephan

--
Stephan Bird MChem(Hons) AMRSC
Currently in Caernarfon, Wales
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SJAB1958
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PostPosted: Fri Jun 01, 2007 8:11 pm    Post subject: Re: Catalysts Query Reply with quote

On 1 Jun, 15:11, Stephan Bird <stephan.j.b...@mad.scientist.comREMOVE>
wrote:
Quote:
On Thu, 31 May 2007 22:58:12 -0700, in
1180677492.424172.144...@k79g2000hse.googlegroups.com SJAB1958

balf...@hotmail.com> wrote:
What is the simplest organic molecule that can catalyse a reaction
from which the same molecule emerges as one of the products?

You might want to look into Soai autocatalysis, e.g
http://dx.doi.org/10.1038/378767a0

Stephan

--
Stephan Bird MChem(Hons) AMRSC
Currently in Caernarfon, Wales

Thanks for the link, pity I cannot access the remainder of the
article, still it is a pointer in the right direction.
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Ron Jones
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PostPosted: Fri Jun 01, 2007 11:35 pm    Post subject: Re: Catalysts Query Reply with quote

SJAB1958 wrote:
Quote:
What is the simplest organic molecule that can catalyse a reaction
from which the same molecule emerges as one of the products?

aryl bromide + CuCN to aryl cyanide + CuBr
- usual cat is pyridine, dmf, etc., but the product often works better.

--
Ron Jones
Process Safety & Development Specialist
Don't repeat history, unreported chemical lab/plant near misses at
http://www.crhf.org.uk
Only two things are certain: The universe and human stupidity; and I'm not
certain about the universe. ~ Albert Einstein
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